If you are a normal private business, first ask: which WHS law applies where the work is happening? For a cafe, ecommerce warehouse, construction subcontractor or office business, that will usually be the state or territory law.
The Commonwealth Act becomes important when the work sits in the Comcare system or connects with Commonwealth workplaces. Think Commonwealth agencies, public authorities, certain self-insured licensees, or contractors working where Commonwealth control is part of the site or activity.